A gas at 4 atm and 27^circ C in a 3 L container is cooled isochorically to -73^circ C . What is the final pressure?
**Thermal equilibrium** achieved when temperatures equal, zeroth law allows definition of temperature, quasi-static process approximates equilibrium at each step, enabling calculation of work as area under P-V curve, reversible processes are quasi-static without dissipative effects. For isochoric: (P₁)/(T₁) = (P₂)/(T₂) . P₁ = 4 atm , T₁ = 27 + 273 = 300 K , T₂ = -73 + 273 = 200 K . (4)/(300) = (P₂)/(200) ⇒ P₂ = (4 × 200)/(300) = (8)/(3) ≈ 2.67 atm . Using first law ΔU = Q - W, W = ∫ P dV, isobaric W = P ΔV, isothermal W = n R T ln(V₂/V₁), adiabatic
Ref: NCERT > Physics Book > Thermodynamics > Zeroth Law Thermal Equilibrium and Quasi-static