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The S_N₁ reaction depends on carbocation stability, with tertiary carbocations being the most stable. This follows from NCERT principle where relation explains outcome clearly for students.
Ref: NCERT Chemistry Textbook for Class XI and XII, Chapter: Some Basic Concepts, Structure of Atom, Periodicity and relevant Chemistry topic, Topic: Mole concept and periodic trends.
SN₁ reactivity depends on carbocation stability: tertiary > secondary > primary.
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Classification and Nomenclature and Isomerism of Haloalkanes
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