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Boiling point of group 14 tetrachlorides (XCl₄) increases with molecular weight due to stronger London forces. SnCl₄ (Sn, heaviest) has the highest boiling point among C, Si, Ge, and Sn.
Ref: NCERT Class 11 Chemistry > Chapter 3: Classification of Elements and Periodicity in Properties > Topic: Nomenclature of Elements with Atomic Number >100
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