The maximum speed of photoelectrons is \( 6.0 \times 10^5 \, \text{m/s} \) when light of wavelength \( 400 \, \text{nm}
**Classical wave theory fails** to explain instant emission, threshold existence, K_max dependence on frequency not intensity, saturation current dependence on intensity. Observations: K_max independent of intensity, exists threshold frequency, emission instantaneous, all explained by photon model E = h f, one photon ejects one electron, energy conservation h f = Φ + K_max. Kₘₐₓ = (1/2) m vₘₐₓ² = (1/2) × 9.11 × 10⁻³¹ × (6.0 × 10⁵)² = 1.6398 × 10⁻¹⁹ J . Kₘₐₓ = (1.6398 × 10⁻¹⁹/1.6 × 10⁻¹⁹) ≈ 1.025 eV . E = (h c/λ) = (1240/400) = 3.1 eV . Φ₀ = E - Kₘₐₓ = 3.1 - 1.025 ≈
Ref: NCERT > Physics Book > Dual Nature of Matter > Photoelectric Effect - Work Function and Threshold