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#organic synthesis

9 public questions tagged with this topic.

Which compound is produced when ethyl magnesium chloride reacts with formaldehyde followed by hydrolysis?

Ethyl magnesium chloride (CH₃CH₂MgCl) reacts with formaldehyde (HCHO), adding the ethyl group to the carbonyl carbon, and hydrolysis yields propan-1-ol (CH₃CH₂CH₂OH).

Ref: NCERT Class 12 Chemistry > Chapter 7: Alcohols, Phenols and Ethers > Topic: Preparation of Alcohols - from Alkenes Haloalkanes Carbonyls Grignard

What is the product when propan-1-ol reacts with excess conc. H₂SO₄ at 140°C?

At 140°C, propan-1-ol undergoes intermolecular dehydration in the presence of conc. H₂SO₄ to form di-n-propyl ether (CH₃CH₂CH₂-O-CH₂CH₂CH₃). Alkene formation occurs at higher temperature (~170°C).

Ref: NCERT Class 12 Chemistry > Chapter 7: Alcohols, Phenols and Ethers > Topic: Chemical Reactions of Alcohols - Dehydration Oxidation Esterification