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Tertiary amines like (CH₃)₃N do not react with HNO₂ to form alcohols, unlike primary aliphatic amines, as per the PDF.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Preparation - Hoffmann Bromamide and Reduction of Nitro Compounds
Tertiary amines like (CH₃CH₂CH₂)₃N do not react with HNO₂ to form alcohols or nitrosamines, as per the PDF’s chemical properties.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Preparation - Hoffmann Bromamide and Reduction of Nitro Compounds
Nitrous acid HNO2 is chemical mutagen acting by oxidative deamination converting primary amino groups to keto oxygen on nitrogenous bases. Adenine deaminates to hypoxanthine pairing as guanine, cytosine to uracil pairing as thymine, guanine to xanthine pairing as guanine analog yet pairing ambiguously. These conversions alter coding specificity because resulting deaminated bases form different hydrogen bond patterns during replication, leading predominantly to transition mutations without causing backbone breakage, distinguishing deaminative mechanism from alkylation or intercalation. This pri
Ref: Watson et al., Molecular Biology of the Gene, 7th ed., Chapter 10: Nitrous Acid Deamination Mechanism
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