Why does 2-nitrophenol have a lower boiling point than 4-nitrophenol?
2-Nitrophenol has intramolecular hydrogen bonding, reducing intermolecular forces and lowering its boiling point, while 4-nitrophenol has intermolecular hydrogen bonding, increasing its boiling point.
Ref: NCERT Class 12 Chemistry > Chapter 7: Alcohols, Phenols and Ethers > Topic: Physical Properties and Acidity of Alcohols and Phenols