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Distillation separates liquids based on differences in their boiling points, vaporizing the lower boiling point liquid first.
Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Purification Methods - Crystallization Distillation Chromatography
A 15°C difference (< 25°C) requires fractional distillation for efficient large-scale separation due to close boiling points.
Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Purification Methods - Crystallization Distillation Chromatography
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