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Acetone (CH₃COCH₃) undergoes self-aldol condensation, forming 4-methylpent-3-en-2-one (CH₃COCH\=C(CH₃)₂) after dehydration.
Ref: NCERT Class 12 Chemistry > Chapter 12: Aldehydes, Ketones and Carboxylic Acids > Topic: Nomenclature, Structure and Preparation of Aldehydes and Ketones
The iodoform test requires a CH₃C\=O group. Pentan-3-one (CH₃CH₂COCH₂CH₃) has no methyl ketone group, unlike the others.
Ref: NCERT Class 12 Chemistry > Chapter 12: Aldehydes, Ketones and Carboxylic Acids > Topic: Nomenclature, Structure and Preparation of Aldehydes and Ketones
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