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Chlorination of pentane favors the secondary position (C₂/C₄) due to stability, forming CH₃CHClCH₂CH₂CH₃ (2-chloropentane) as the major product.
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Classification and Nomenclature and Isomerism of Haloalkanes
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