For an exothermic reaction at constant pressure, what is the relationship between Δ H and Δ U?
For an exothermic reaction, Δ H < 0. If Δ n_g < 0 (fewer gas moles in products), Δ H < Δ U because Δ H = Δ U + Δ n_g RT and Δ n_g RT < 0. This follows from latest NCERT 2026-27 principle explaining the concept clearly for NEET students in simple steps as per rationalized syllabus.
Ref: NCERT Chemistry Textbook - Latest Edition for Academic Session 2026-27 (Rationalized Textbook for Class XI and XII)Topic: Mole concept, atomic structure, chemical formulas like H₂O, CO₂, CH₃CH₂NH₂ and periodic trends.