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#electron gain enthalpy

6 public questions tagged with this topic.

Which group 17 element has the highest electron affinity despite not having the most negative electron gain enthalpy?

Electron affinity is the energy change for X + e⁻ -> X⁻. Cl has the highest electron affinity due to its balance of size and nuclear charge, though F’s electron gain enthalpy is less negative due to repulsion.

Ref: NCERT Class 11 Chemistry > Chapter 3: Classification of Elements and Periodicity in Properties > Topic: Electron Gain Enthalpy and Electronegativity and Valency

Arrange F, Cl, Br in order of decreasing electron gain enthalpy (most negative to least negative).

Electron gain enthalpy becomes less negative down group 17 due to increasing atomic size. Cl has the most negative value due to optimal nuclear charge and size, followed by F (less negative due to electron repulsion in its compact 2p orbitals), then Br. Order: Cl > F > Br.

Ref: NCERT Class 11 Chemistry > Chapter 3: Classification of Elements and Periodicity in Properties > Topic: Electron Gain Enthalpy and Electronegativity and Valency

Which element exhibits the most negative electron gain enthalpy?

Electron gain enthalpy becomes more negative across a period and less negative down a group. Among O, S, F, and Cl, Cl (group 17, period 3) has the most negative value due to its high effective nuclear charge and smaller size than S.

Ref: NCERT Class 11 Chemistry > Chapter 3: Classification of Elements and Periodicity in Properties > Topic: Electron Gain Enthalpy and Electronegativity and Valency