Which amine has the highest boiling point among the following?
Primary amines like CH₃CH₂CH₂NH₂ have higher boiling points due to extensive hydrogen bonding compared to secondary and tertiary amines, as per the PDF.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Reaction with Nitrous Acid and Diazonium Salts - Part 1