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Tertiary carbocations are more stable due to hyperconjugation and inductive effects. (CH₃)₃C⁺ (tertiary) is more stable than primary or secondary ones.
Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Electronic Effects - Inductive Mesomeric Hyperconjugation and Resonance
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