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This is the Sandmeyer reaction. Aniline forms a diazonium salt with NaNO₂ and HCl , which reacts with CuCl to yield chlorobenzene ( C₆H₅Cl ).
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Physical Properties - Boiling Point Dipole Moment Solubility
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