Practice question
Question
A gas mixture has equal masses of helium and nitrogen at 300 K. What is the ratio of their rms speeds? (Atomic mass: He = 4 u, N₂ = 28 u)
Explanation
**Molecular mass and density** relation ρ = P M/(R T) allows density calculation, ideal gas law also P = n k_B T where n number density, molecular mass determines mass per molecule, density increases with pressure and decreases with temperature, inverse T dependence. v_rms ∝ (1)/(√(m)), v_Hev_N₂ = √(m_N)₂m_He.v_Hev_N₂ = √((28)/(4)) = √(7) ≈ 2.645. Substituting values gives 2.65:1, which matches expected kinetic theory result, confirming mean free path λ = 1/(√2 n π d²), ideal gas law P V = n R T and v_rms = √(3 R T/M) relations.
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