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Tertiary halides like (CH₃)3CCl ionize readily via SN₁ , forming AgCl precipitate instantly with AgNO₃ .
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Physical Properties - Boiling Point Dipole Moment Solubility
C₆H₅Cl (chlorobenzene) has a strong C-Cl bond due to sp² hybridization and resonance, making it unreactive in SN₁ with AgNO₃ .
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Nature of C-X Bond and Methods of Preparation
No reaction with Lassaigne’s test indicates no halogens. CH₃CH₂COCH₂CH₃ (pentan-3-one) is a ketone consistent with C₅H₁₀O.
Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Isomerism - Structural Isomerism - Chain Position Functional Metamerism
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