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Methylamine (CH₃NH₂), a primary aliphatic amine, reacts with HNO₂ to form methanol (CH₃OH) and N₂, as per the PDF.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Preparation - Hoffmann Bromamide and Reduction of Nitro Compounds
Ethylamine (CH₃CH₂NH₂) forms ethyl isocyanide (CH₃CH₂NC) in the carbylamine reaction, as per the PDF’s chemical properties.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Nomenclature, Structure and Preparation - Ammonolysis and Gabriel Synthesis
Propan-1-amine (CH₃CH₂CH₂NH₂) forms propyl isocyanide (CH₃CH₂CH₂NC) in the carbylamine reaction, as per the PDF.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Nomenclature, Structure and Preparation - Ammonolysis and Gabriel Synthesis
LiAlH₄ reduces carboxylic acids to primary alcohols. Propanoic acid (CH₃CH₂COOH) yields propan-1-ol (CH₃CH₂CH₂OH).
Ref: NCERT Class 12 Chemistry > Chapter 12: Aldehydes, Ketones and Carboxylic Acids > Topic: Reactions due to α-Hydrogen - Aldol, Cannizzaro and Acidity of Carboxylic Acids
Heating calcium acetate ((CH₃COO)₂Ca) decarboxylates it to acetone (CH₃COCH₃), so acetone remains unchanged in this context, but the reaction confirms its formation.
Ref: NCERT Class 12 Chemistry > Chapter 12: Aldehydes, Ketones and Carboxylic Acids > Topic: Reactions due to α-Hydrogen - Aldol, Cannizzaro and Acidity of Carboxylic Acids
NaNH₂ (strong base) promotes E₂ elimination in CH₃CH₂CHClCH₂CH₃ , forming CH₃CH₂CH=CHCH₃ (2-pentene) per Zaitsev's rule.
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Polyhalogen Compounds - Chloroform Iodoform DDT Freons
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