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Aniline (C₆H₅NH₂) with Br₂ in acetic acid (less reactive medium) forms p-bromoaniline predominantly due to the ortho-para directing effect of −NH₂, as per the PDF.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Chemical Reactions - Carbylamine Reaction and General Reactions
Aniline (C₆H₅NH₂, 6C) forms 2,4,6-tribromoaniline (C₆H₂Br₃NH₂), retaining 6 carbon atoms, as per the PDF’s chemical properties.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Chemical Reactions - Carbylamine Reaction and General Reactions
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