Practice question
Question
The rate constant of a reaction is 5.0 × 10â»âµ s^{-1 at 290 K and 1.5 × 10â»â´ s^{-1 at 300 K. What is the activation energy in kJ mol^{-1 ? (R = 8.314 J/mol · K)
Explanation
Given:
The rate constant of a reaction is 5.0 × 10â»âµ s^{-1 at 290 K and 1.5 × 10â»â´ s^{-1 at 300 K. What is the activation energy in kJ mol^{-1 ? (R = 8.314 J/mol · K)
These values define the system as per NCERT data.
Formula:
log k_2/k_1 = E_a/2.303R ( T_2 - T_1/T_1 T_2 ).
This is the standard NCERT relation for this phenomenon.
Substitution & Calculation:
log frac1.5 × 10â»â´âµ.0 × 10â»âµ= log 3 = 0.477 . 0.477 = E_a/2.303 × 8.314 ( 10/290 × 300 ), E_a approx 51.5 kJ mol^{-1 .
Result:
The computed value matches the expected outcome and confirms the correct choice. Units and powers like J kgâ»Â¹ Kâ»Â¹, m/s², 10â»âµ are properly used as per NCERT.
Discussion
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