Practice question
Question
The rate constant of a reaction is 1.2 × 10â»â´ s^{-1 at 320 K and 4.8 × 10â»â´ s^{-1 at 330 K. What is the activation energy in kJ mol^{-1 ? (R = 8.314 J/mol · K)
Explanation
Given:
The rate constant of a reaction is 1.2 × 10â»â´ s^{-1 at 320 K and 4.8 × 10â»â´ s^{-1 at 330 K. What is the activation energy in kJ mol^{-1 ? (R = 8.314 J/mol · K)
These values define the system as per NCERT data.
Formula:
log k_2/k_1 = E_a/2.303R ( T_2 - T_1/T_1 T_2 ).
This is the standard NCERT relation for this phenomenon.
Substitution & Calculation:
log frac4.8 × 10â»â´Â¹.2 × 10â»â´= log 4 = 0.602 . 0.602 = E_a/2.303 × 8.314 ( 10/320 × 330 ), E_a approx 64.7 kJ mol^{-1 .
Result:
The computed value matches the expected outcome and confirms the correct choice. Units and powers like J kgâ»Â¹ Kâ»Â¹, m/s², 10â»âµ are properly used as per NCERT.
Discussion
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