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The longest chain with the ketone group has 5 carbons (pentan-2-one), with the carbonyl on C-2: pentan-2-one.
Ref: NCERT Class 12 Chemistry > Chapter 12: Aldehydes, Ketones and Carboxylic Acids > Topic: Chemical Reactions - Reduction, Oxidation and Tests - Tollens, Fehling, Iodoform
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