At 298 K, the bond dissociation energies of C–H, C–C and C=C are 415, 344 and 615 kJ mol ⁻¹ , respectively. The enthalpy
The principle of molecular bonding explains that hybridization and orbital overlap dictate geometry and reactivity. Hence Option NAT fits best because it satisfies bonding and stability criteria, as documented in authoritative sources on chemistry.
Ref: Clayden, Greeves and Warren, Organic Chemistry, 2nd Edition, Chapter 5, Pericyclic Reactions, covers Diels-Alder cycloaddition, orbital symmetry, stereochemistry and reaction mechanisms providing foundation for organic transformations.