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2-Nitrophenol has intramolecular hydrogen bonding, reducing intermolecular forces and lowering its boiling point, while 4-nitrophenol has intermolecular hydrogen bonding, increasing its boiling point.
Ref: NCERT Class 12 Chemistry > Chapter 7: Alcohols, Phenols and Ethers > Topic: Physical Properties and Acidity of Alcohols and Phenols
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