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#ketone

11 public questions tagged with this topic.

Which ketone is least reactive towards nucleophilic addition?

As steric hindrance increases, reactivity decreases. Benzophenone has bulky phenyl groups, making it the least reactive. This follows from NCERT principle where relation explains outcome clearly for students.

Ref: NCERT Chemistry Textbook for Class XI and XII, Chapter: Some Basic Concepts, Structure of Atom, Periodicity and relevant Chemistry topic, Topic: Mole concept and periodic trends.

Which carboxylic acid produces a ketone with eight carbon atoms when its calcium salt is heated?

Pentanoic acid (CH₃CH₂CH₂CH₂COOH) forms calcium pentanoate, which decarboxylates to heptan-4-one (CH₃CH₂CH₂COCH₂CH₂CH₃), an eight-carbon ketone.

Ref: NCERT Class 12 Chemistry > Chapter 12: Aldehydes, Ketones and Carboxylic Acids > Topic: Reactions due to α-Hydrogen - Aldol, Cannizzaro and Acidity of Carboxylic Acids

Which ketone reacts with itself under basic conditions to form a nine-carbon β-hydroxy ketone?

Hexan-3-one (CH₃CH₂COCH₂CH₂CH₃) undergoes self-aldol condensation to form 4-hydroxy-3-propylheptan-5-one (CH₃CH₂C(OH)(CH(CH₂CH₃)COCH₂CH₃)CH₂CH₃), a nine-carbon β-hydroxy ketone.

Ref: NCERT Class 12 Chemistry > Chapter 12: Aldehydes, Ketones and Carboxylic Acids > Topic: Nomenclature, Structure and Preparation of Aldehydes and Ketones