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Pentane ( CH₃CH₂CH₂CH₂CH₃ ) has three unique carbon positions for Cl substitution (C₁/C₅, C₂/C₄, C₃), yielding 3 isomers.
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Classification and Nomenclature and Isomerism of Haloalkanes
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