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In [Fe(NH₃)5Cl]Cl₂, the 2 Cl− ions outside the coordination sphere are ionizable and form AgCl, while the inner Cl is a ligand. Thus, 2 moles precipitate.
Ref: NCERT Class 12 Chemistry > Chapter 5: Coordination Compounds > Topic: Werner's Theory and Definitions - Ligands Coordination Number
In [Cr(H₂O)5Cl]Cl₂, the 2 Cl− ions outside the coordination sphere are ionizable and form AgCl, while the inner Cl is a ligand. Thus, 2 moles precipitate.
Ref: NCERT Class 12 Chemistry > Chapter 5: Coordination Compounds > Topic: Werner's Theory and Definitions - Ligands Coordination Number
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