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#organic chemistry questions

2 public questions tagged with this topic.

Which aldehyde forms a racemic mixture when treated with NH₂OH?

Butanal (CH₃CH₂CH₂CHO) reacts with NH₂OH to form an oxime (CH₃CH₂CH₂CH\=NOH), but the carbonyl carbon becomes chiral in the intermediate, yielding a racemic mixture.

Ref: NCERT Class 12 Chemistry > Chapter 12: Aldehydes, Ketones and Carboxylic Acids > Topic: Reactions due to α-Hydrogen - Aldol, Cannizzaro and Acidity of Carboxylic Acids

Which compound with C₄H₈ has a degree of unsaturation of 1 and can be separated from its chain isomer by simple distilla

CH₂=CHCH₂CH₃ (but-1-ene) has one double bond (degree = 1). Its chain isomer, 2-methylpropene (CH₃C(CH₃)=CH₂), has a similar boiling point, but cyclic isomers like cyclobutane can be separated by simple distillation due to a larger boiling point difference.

Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Isomerism - Structural Isomerism - Chain Position Functional Metamerism