Practice question
Question
A reaction has k = 1.0 × 10â»Â³ s^{-1 at 27°C and E_a = 52 kJ mol^{-1 . What is the temperature (in °C) when k = 3.0 × 10â»Â³ s^{-1 ? (R = 8.314 J/mol · K)
Explanation
Given:
A reaction has k = 1.0 × 10â»Â³ s^{-1 at 27°C and E_a = 52 kJ mol^{-1 . What is the temperature (in °C) when k = 3.0 × 10â»Â³ s^{-1 ? (R = 8.314 J/mol · K)
These values define the system as per NCERT data.
Formula:
log frac3.0 × 10â»Â³Â¹.0 × 10â»Â³= 52000/2.303 × 8.314 ( T_2 - 300/300 T_2 ).
This is the standard NCERT relation for this phenomenon.
Substitution & Calculation:
0.477 = 2717.5 ( T_2 - 300/300 T_2 ), T_2 approx 316 K = 43 °C .
Result:
The computed value matches the expected outcome and confirms the correct choice. Units and powers like J kgâ»Â¹ Kâ»Â¹, m/s², 10â»âµ are properly used as per NCERT.
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